全文获取类型
收费全文 | 3358篇 |
免费 | 105篇 |
国内免费 | 645篇 |
专业分类
化学 | 1754篇 |
晶体学 | 9篇 |
力学 | 57篇 |
综合类 | 1篇 |
数学 | 41篇 |
物理学 | 2246篇 |
出版年
2024年 | 8篇 |
2023年 | 88篇 |
2022年 | 46篇 |
2021年 | 52篇 |
2020年 | 85篇 |
2019年 | 75篇 |
2018年 | 95篇 |
2017年 | 77篇 |
2016年 | 123篇 |
2015年 | 129篇 |
2014年 | 147篇 |
2013年 | 208篇 |
2012年 | 256篇 |
2011年 | 367篇 |
2010年 | 205篇 |
2009年 | 251篇 |
2008年 | 257篇 |
2007年 | 268篇 |
2006年 | 216篇 |
2005年 | 136篇 |
2004年 | 117篇 |
2003年 | 123篇 |
2002年 | 117篇 |
2001年 | 90篇 |
2000年 | 73篇 |
1999年 | 52篇 |
1998年 | 56篇 |
1997年 | 45篇 |
1996年 | 50篇 |
1995年 | 56篇 |
1994年 | 42篇 |
1993年 | 30篇 |
1992年 | 25篇 |
1991年 | 36篇 |
1990年 | 13篇 |
1989年 | 13篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 4篇 |
1985年 | 9篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1974年 | 3篇 |
1973年 | 5篇 |
排序方式: 共有4108条查询结果,搜索用时 109 毫秒
991.
Highly Sensitive Flexible Pressure Sensors based on Graphene/Graphene Scrolls Multilayer Hybrid Films 下载免费PDF全文
Yi-heng Zhai Tao Wang Zhi-kai Qi Xiang-hua Kong Hang-xun Xu Heng-xing Ji 《化学物理学报(中文版)》2020,33(3):365-370
In recent years, flexible pressure sensors have attracted much attention owing to their potential applications in motion detection and wearable electronics. As a result, important innovations have been reported in both conductive materials and the underlying substrates, which are the two crucial components of a pressure sensor. 1D materials like nanowires are being widely used as the conductive materials in flexible pressure sensors, but such sensors usually exhibit low performances mainly due to the lack of strong interfacial interactions between the substrates and 1D materials. In this paper, we report the use of graphene/graphene scrolls hybrid multilayers films as the conductive material and a micro-structured polydimethylsiloxane substrate using Epipremnum aureum leaf as the template to fabricate highly sensitive pressure sensors. The 2D structure of graphene allows to strongly anchor the scrolls to ensure the improved adhesion between the highly conductive hybrid films and the patterned substrate. We attribute the increased sensitivity (3.5 kPa\begin{document}$ ^{-1} $\end{document} ), fast response time (\begin{document}$ < $\end{document} 50 ms), and the good reproducibility during 1000 loading-unloading cycles of the pressure sensor to the synergistic effect between the 1D scrolls and 2D graphene films. Test results demonstrate that these sensors are promising for electronic skins and motion detection applications. 相似文献
992.
Exotic electronic excitations beyond normal selection rules would open novel possibilities for photoenergy conversion. The large intensity gradient of electromagnetic fields resulting from the confinement of localized surface plasmons at the molecular scale could exceed the limit of light–matter interactions via modification of electronic excitation selection rules. We discuss the possible application of surface-enhanced Raman scattering as a probe for exotic electronic excitations by reviewing studies on small numbers of molecules at the surface of plasmonic metal nanostructures. Future innovative photo-functionalization is also discussed by considering the excited states produced by the exotic electronic excitations. 相似文献
993.
A 3D printable self-healing composite conductive polymer for sensitive temperature detection 总被引:1,自引:0,他引:1
Recent development of self-healing material has attracted tremendous attention,owing to its biomimetic ability to restore structure and functionality when encountering damages.Here,we develop a threedimensional(3D)printable self-healing composite conductive polymer by mixing hydrogen-bond-based supramolecular polymer with low-cost carbon black.It has a room-temperature self-healing capability in both conductivity and mechanical property,while its shear-thinning behavior enables fabrication of a self-healable circuit by 3D printing technology.As an application,the circuit shows an excellent temperature-dependent behavior of the resistance,indicating its great potential fo r practical application in the artificial intelligence field. 相似文献
994.
《中国化学快报》2020,31(9):2325-2329
As electrodes, two-dimensional materials show special advantages including the infinite planar lengths, broad electrochemical window, large surface–volume ratio, and much exposed active sites. In theory, the two-dimensional materials consist of the elements with high electronegativity may absorb more Na atoms, resulting in a high battery storage capacity. Based on the above idea, we selected the two dimensional metallic PS2 with 1T-Type structure as an anode material, and explored its potential applications as an electrode material for Na-ion battery through first-principle calculations. As we expected, when two dimensional PS2 is used as an anode in Na-ion battery, it can adsorb maximum three layers of sodium atoms on both sides of the monolayer, resulting in a maximum theoretical capacity of 1692 mAh/g. Furthermore, it also possesses a rather small sodium diffusion barrier of 0.17 eV, a low average open-circuit voltage of 0.18 V, and a relatively small lattice changes within 13% during the intercalation of Na. These results suggested that the two dimensional PS2 is a potentially excellent Na-ion battery anode. Our idea of designing two-dimensional anode materials with high storage capacity may provide some references for designing the next generation anode materials of metal-ion batteries. 相似文献
995.
用 XPS测定了 LnCu2O4(Ln=Gd, Nd)的内层和价层电子能谱,观察到 LnCu2O4中稀土金属的 3d电子结合能比相应的稀土金属简单氧化物的 3d结合能低 0.8~ 0.9 eV,而 Cu的 2p电子结合能比 CuO的高 0.4~ 0.5 eV,因此推断在 LnCu2O4的 Ln- O- Cu链中存在 Cu→ O→ Ln电荷转移 .XPS分析还表明 LnCu2O4的 Cu原子上有较低的电荷密度,但不存在混合价态 .此外,通过比较价电子能谱,发现 NdCu2O4的 Ln 4f Cu 3d O 2p价带中心比 GdCu2O4的价带中心向 Fermi能级移近了 3.4 eV,而且 NdCu2O4的价带谱更窄 . 相似文献
996.
轴向配体在决定血红素蛋白结构和性能方面的作用引起人们的兴趣[1] .细胞色素 c是一个重要的电子传递蛋白 ,在天然状态下轴向配体 His 1 8和 Met80与血红素的 Fe原子配位 . UV光谱和 NMR谱显示氧化态细胞色素 c配位的 Met80在 p H大于 9或强外源配体存在时较易被取代[2 ] .人们对外源配体配位引发细胞色素 c的构象的研究得到一些重要的结构特征 [3,4 ] .但对整个蛋白溶液结构完整精确的描述和血红素电子结构的研究还很少 .此外 ,细胞色素 c在重折叠过程中形成组氨酸配位的中间体 ,而咪唑能捕获和阻断中间体的形成 .为此 ,本文对咪唑 -… 相似文献
997.
Metal-oxide-silicon dosimeters with a very thick gate oxide in a stack-connected configuration are studied with respect to their capability to measure a low dose. It is shown that if the temperature is controlled to ±5°C during reading a dose as low as 10−4 Gy can be measured with 10% accuracy. 相似文献
998.
V. A. Avantaggiati F. Frezza G. Schettini 《International Journal of Infrared and Millimeter Waves》2001,22(7):1095-1117
A full-wave method for the two-dimensional scattering problem by a perfectly conducting circular cylinder is presented, providing an exact solution for the Helmholtz equation in very general cases. The method is based on the Fourier series expression of the boundary conditions (Dirichlet and Neumann) generated by an arbitrary, finite-power, incident beam, and the analysis is performed in the complex plane of the analytic continuation of a space spectral variable. This approach allows us to define an analytic continuation for cylindrical wave expansions, working with lossy propagation media and with a full incident spectrum, including inhomogeneous waves, both in E and in H polarization. Convergence of the modal expansion is investigated, to verify that very weak hypotheses are needed, and no geometrical or paraxial approximation is required. Extact expressions for the expansion coefficients are given, in terms of complex intergrations involving the Fourier spectrum of the incident beam. 相似文献
999.
Y. Dagan A. Kohen G. Deutscher 《The European Physical Journal B - Condensed Matter and Complex Systems》2001,19(3):353-356
We have measured I(V) characteristics of c-axis planar tunnel junctions on Y1Ba2Cu3O 7 - δ films. Our results and their analysis provide experimental support for the importance of the two-dimensional character of
the YBCO band structure, and a method to measure the ratio between the Fermi energy of YBCO and the barrier height. The analysis
is based on the relation between the linear conductance background, related to the inelastic tunneling component, and the
zero bias conductance, related to the elastic one.
Received 24 September 2000 and Received in final form 15 November 2000 相似文献
1000.
J.L. Ricardo-Chávez G.M. Pastor 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,16(1):169-172
The properties of magnetic impurities in small metallic clusters are investigated in the framework of the Anderson model by
using exact diagonalization methods. Parameters representative of the Kondo limit are considered. The spin gap ΔE = E(S=1, 3/2) - E(S=0, 1/2) shows a remarkable band-filling dependence that can be interpreted in terms of the cluster-specific conduction-electron
spectrum. Finite-temperature properties such as the magnetic susceptibility and specific heat are calculated exactly in the
canonical and grand canonical ensembles. The structural dependence is illustrated.
Received 30 November 2000 相似文献